T. Maurice et al., MID INFRARED OPTICAL INVESTIGATIONS OF PB1-XEUXSE PARALLEL-TO BAF2 THIN-FILMS GROWN BY MBE, Physica status solidi. b, Basic research, 209(2), 1998, pp. 523-534
IV-VI semiconductor compounds are interesting in the mid-infrared (MIR
) range for optoelectronic applications because these compounds have a
narrow direct bandgap in this frequency range. Our study presents the
determination of the optical constants dispersion which are the absor
ption coefficient alpha(omega) and the refractive index n(omega) in th
e MIR range for PbSe and Pb1-xEuxSe thin films (x < 5%) deposited by m
olecular beam epitaxy (MBE) on (111) BaF2 substrates. X-ray high resol
ution diffraction (HRD) measurements gave information on the structura
l quality. Transmission experiments have been performed on these sampl
es from 800 to 5000 cm(-1) at different temperatures. The treatment of
experimental transmission spectra has been done by theoretical calcul
ations. The model applying to determine alpha(omega) and n(omega) is b
ased on the nonparabolic two-band model (only four fitting parameters)
. Using the transfer-matrix method, the best fit to experimental trans
mission spectra provides alpha(omega) and n(omega). The results are in
agreement with those already published on PbSe materials and are new
for Pb1-xEuxSe epilayers. Moreover, the dependence of the band gap eps
ilon(g) on x and T is established for Pb1-xEuxSe (x < 5%).