SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL 2,3-DISTIBENE-1,4-DIONE COMPLEX, [PT(PET3)(2)(ETA(2)-(BUC)-C-T(O)SB=SBC(O)BU-T))]

Authors
BLACK SJ HIBBS DE HURSTHOUSE MB JONES C STEED JW
Citation
Sj. Black et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL 2,3-DISTIBENE-1,4-DIONE COMPLEX, [PT(PET3)(2)(ETA(2)-(BUC)-C-T(O)SB=SBC(O)BU-T))], Chemical communications, (20), 1998, pp. 2199-2200
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
20
Year of publication
1998
Pages
2199 - 2200
Database
ISI
SICI code
1359-7345(1998):20<2199:SASCOA>2.0.ZU;2-V
Abstract
The reaction of cis-[PtCl2(PEt3)(2)] with 2 equiv. of 2)-OC(Bu-t)EC(Bu -t)O}(DME)(0.5)](2)}(infinity)](,) E = Sb Or AS, affords either the fi rst distibene-dione complex, s-[Pt(PEt3)(2){eta(2)-(BuC)-C-t(O)Sb=SbC( O)Bu-t}], or the related diarsenide-dione bridged complex, trans-[{Pt( PEt3)Cl}(2){mu-eta(1), eta(1)-(BuC)-C-t(O)-AsAsC(O)Bu-t}], the X-ray c rystal structures of which are described.