SYNTHESIS OF A CHIRAL PYRIDYLPHOSPHINE LIGAND AND A COMPARISON OF ITSRHODIUM COMPLEX WITH THE STRUCTURALLY SIMILAR ARYLPHOSPHINE RHODIUM CATALYSTS IN THE ASYMMETRIC HYDROGENATION OF 2-(6'-METHOXY-2'-NAPHTHYL)PROPENOIC ACID

Authors
HU WH PAI CC CHEN CC XUE GP CHAN ASC
Citation
Wh. Hu et al., SYNTHESIS OF A CHIRAL PYRIDYLPHOSPHINE LIGAND AND A COMPARISON OF ITSRHODIUM COMPLEX WITH THE STRUCTURALLY SIMILAR ARYLPHOSPHINE RHODIUM CATALYSTS IN THE ASYMMETRIC HYDROGENATION OF 2-(6'-METHOXY-2'-NAPHTHYL)PROPENOIC ACID, Tetrahedron : asymmetry, 9(18), 1998, pp. 3241-3246
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
18
Year of publication
1998
Pages
3241 - 3246
Database
ISI
SICI code
0957-4166(1998)9:18<3241:SOACPL>2.0.ZU;2-Y
Abstract
A chiral pyridylphosphine ligand is[di-3'-(2',6'-dimethoxypyridyl)phos phino]pentane was synthesized. The rhodium catalyzed asymmetric hydrog enation of 2-(6'-methoxy-2'-naphthyl)propenoic acid was studied by usi ng this ligand in comparison with the structurally similar Skewphos an alogs. (C) 1998 Elsevier Science Ltd. All rights reserved.