A NOVEL TYPE OF PD C-CATALYZED HYDROGENATION USING A CATALYST POISON - CHEMOSELECTIVE INHIBITION OF THE HYDROGENOLYSIS FOR O-BENZYL PROTECTIVE GROUP BY THE ADDITION OF A NITROGEN-CONTAINING BASE/

Authors
SAJIKI H HIROTA K
Citation
H. Sajiki et K. Hirota, A NOVEL TYPE OF PD C-CATALYZED HYDROGENATION USING A CATALYST POISON - CHEMOSELECTIVE INHIBITION OF THE HYDROGENOLYSIS FOR O-BENZYL PROTECTIVE GROUP BY THE ADDITION OF A NITROGEN-CONTAINING BASE/, Tetrahedron, 54(46), 1998, pp. 13981-13996
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
46
Year of publication
1998
Pages
13981 - 13996
Database
ISI
SICI code
0040-4020(1998)54:46<13981:ANTOPC>2.0.ZU;2-D
Abstract
A mild and chemoselective hydrogenation method for a variety of reduci ble functional groups distinguishing front aliphatic and aromatic benz yl ethers was accomplished by the addition of an appropriate nitrogen- containing base to the Pd/C-catalyzed hydrogenation system. (C) 1998 E lsevier Science Ltd. All rights reserved.