ORGANOPHOSPHORUS COMPOUNDS .117. HYDROSTANNYLATION OF BECKER-TYPE PHOSPHAALKENES

Authors
SCHMITZ M GOLLER R REGITZ M
Citation
M. Schmitz et al., ORGANOPHOSPHORUS COMPOUNDS .117. HYDROSTANNYLATION OF BECKER-TYPE PHOSPHAALKENES, Synthesis, (4), 1997, pp. 455
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
4
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):4<455:OC.HOB>2.0.ZU;2-O
Abstract
Reactions of Becker-type phosphaalkenes 5a-e with triorganotin hydride s 1a,b proceed through 1,2-addition to furnish the stannylphosphanes 7 a-j. Analogous use of the diorganotin dihydrides II and 14 gives rise to the hydridostannylphosphanes 12 and 15. The product 16 of a double addition can also be isolated from the reaction of dimethyltin dihydri de 14 with the phosphaalkene 5a.