AZIRIDINATION OF ALPHA,BETA-UNSATURATED KETONES

Authors
FIORAVANTI S PELLACANI L TABANELLA S TARDELLA PA
Citation
S. Fioravanti et al., AZIRIDINATION OF ALPHA,BETA-UNSATURATED KETONES, Tetrahedron, 54(46), 1998, pp. 14105-14112
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
46
Year of publication
1998
Pages
14105 - 14112
Database
ISI
SICI code
0040-4020(1998)54:46<14105:AOAK>2.0.ZU;2-G
Abstract
alpha,beta-Unsaturated ketones are aziridinated by [(arenesulphonyl)ox y]carbamates and CaO (or Cs2CO3) or by N3CO2Et photolysis. A remote ch iral center induced up to 74% de. Bis-unsaturated substrates showed sc arce regioselectivity under all conditions. (C) 1998 Elsevier Science Ltd. AII rights reserved.