Ab-initio potential energy curves and coupling matrix elements of the
molecular states involved in the collision of the Si2+ multicharged io
n on atomic hydrogen have been determined by means of configuration in
teraction methods. The total and partial electron capture cross sectio
ns have been determined using a semi-classical approach in the 0.1-100
0 eV center-of-mass energy range. The results are in fair agreement wi
th previous works and show the influence of radial, rotational as well
as translational effects. (C) 1998 Elsevier Science B.V. All rights r
eserved.