A production method of carbon nanotubes using the catalytic decomposit
ion of acetylene has been developed. Metal clusters are formed by lase
r vaporisation of solid nickel in situ in a hot reaction tube containi
ng a mixture of acetylene and argon. The laser generated clusters act
as catalysts for the growth of nanotubes. With this method multi-walle
d tubes were obtained with inner diameters of 3-10 nm and outer diamet
ers of 10-100 nm. Transmission electron microscopy shows that the tube
s are highly graphitic. The results obtained are explained by a growth
model. (C) 1998 Elsevier Science B.V. All rights reserved.