M. Baer et al., TIME-DEPENDENT AND TIME-INDEPENDENT APPROACHES TO STUDY EFFECTS OF DEGENERATE ELECTRONIC STATES, The Journal of chemical physics, 109(16), 1998, pp. 6550-6556
Two types of phases are discussed in this article: (1) The topological
phase as introduced by Berry [Proc. R. Sec. London, Ser. A 392, 35(19
84)] and Aharonov and Anandan [Phys. Rev. Lett. 58, 1593 (1987)] and (
2) the Longuet-Higgins phase [Proc. R. Sec. London, Ser. A 344, 147 (1
975)]. The two types of phases have a common origin, namely the multiv
aluedness of the electronic adiabatic basis, a phenomenon associated w
ith the existence of a degeneracy in configuration space. It will be s
hown, by studying an electronic model Hamiltonian that arises from a t
wo-state approximation to the Mathieu equation, that the two phases di
ffer from each other substantially, coinciding only in the adiabatic l
imit ripen completion of a cycle. (C) 1998 American Institute of Ph, s
ics. [S0021-9606(98)30440-7].