With a sophisticated analysis we determine the photospheric metal abun
dances of active stars to investigate the abundance stratification in
active stellar atmospheres. For selected single stars and RS CVn binar
ies we have taken high-resolution, high-SN and partially phase-resolve
d spectra of the entire visible range. With a purely spectroscopic, se
lf-consistent method based on line profile synthesis and an equivalent
width analysis, we derive the effective temperature T-eff, surface gr
avity log g, microturbulence xi(t) and the abundances of Fe, Mg and Si
with high internal accuracy (Delta T-eff similar or equal to 70K, Del
ta log g similar or equal to 0.1 dex, Delta xi(t) similar or equal to
0.1 km/s, Delta[Fe/H], Delta[Mg/H], Delta[Si/H] similar or equal to 0.
05 dex). Stellar parameters and metal abundances are obtained for the
single stars beta Get, kappa Cet and pi(1) UMa as well as for the RS C
Vn binaries AY Get, VY Ari, EI Eri, IM Peg, lambda And and II Peg. The
effect of stellar activity features (spots and plages) on the derived
parameters is investigated by phase-resolved spectroscopy; we find th
at one out of four systems shows a significant variation of the Mg and
Si abundances with rotational phase. The results help solving the puz
zle about the photospheric Fe abundances of RS CVn binaries; specifica
lly, we obtain [Fe/H] greater than or equal to -0.4 for all systems, i
ndicating that they definitely are not metal-poor. In II Peg and lambd
a And, the metals are strongly depleted in the corona relative to the
photosphere; in beta Cet and pi(1) UMa, Fe and Si are weakly depleted,
but Mg is enhanced (with 1 sigma significance). The abundance stratif
ications are discussed in terms of the FIP-effect and the hydrostatic
equilibrium stratification.