DYNAMIC PROPERTIES OF N AND O 1S(-1) SIGMA-U-ASTERISK SHAPE RESONANCES IN N-2 AND CO2 MOLECULES

Authors
PAVLYCHEV AA FOMINYKH NG WATANABE N SOEJIMA K SHIGEMASA E YAGISHITA A
Citation
Aa. Pavlychev et al., DYNAMIC PROPERTIES OF N AND O 1S(-1) SIGMA-U-ASTERISK SHAPE RESONANCES IN N-2 AND CO2 MOLECULES, Physical review letters, 81(17), 1998, pp. 3623-3626
Citations number
17
Categorie Soggetti
Physics
Journal title
Physical review letters → ACNP
ISSN journal
00319007
Volume
81
Issue
17
Year of publication
1998
Pages
3623 - 3626
Database
ISI
SICI code
0031-9007(1998)81:17<3623:DPONAO>2.0.ZU;2-Z
Abstract
An essential correlation between intramolecular interference of photoe lectron waves and core-hole molecular relaxation is revealed by analyz ing the partial wave composition of the calculated angular distributio n of photoelectrons in the N and O 1s(-1)sigma(u) shape resonances of aligned N-2 and CO2. The dominance of coherent (N-2) and incoherent ( CO2) interference is revealed, pf and spd hybridization controls the m ain direction of photoelectron emission from the N and O K shell, resp ectively. [S0031-9007(98)07498-5].