Zq. Zhou et al., THE SEPARATION OF THE NEW CHIRAL METAL CLUSTER (MU(3)-SE)RUCOW (CO)(8)-C5H4C(O)CH3 ON AN AMYLOPECTIN TRIS-(PHENYLCARBAMATE) CHIRAL COLUMN BY HPLC, Journal of liquid chromatography & related technologies, 21(19), 1998, pp. 3021-3030
Citations number
10
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
The preparation of amylopection tris(phenylcarbamate) (ATP) chiral sta
tionary phases(CSPs) coated on a small-particle (5 mu m, 120 Angstrom)
spherical silica support, according to a process that is reported, is
presented. A new chiral tetrahedral cluster (mu(3)-Se)RuCoW(CO)(8)C5H
4C(O)CH3 2 which was synthesized by the thermal reaction of the precur
sor (mu(3)-Se)RuCo2(CO)(9) 1 with the functionally substituted cyclope
ntadienyl tricarbonyl metal complex anions [W(CO)(3)C5B4C(O)CH3](-) is
resolved on the amylopectin tris (phenylcarbamate) chiral stationary
phases.