SYNTHESIS OF HETEROPOLYOXOMETALATE-PILLARED MG AL, MG/GA, AND ZN/AL LAYERED DOUBLE HYDROXIDES VIA LDH-HYDROXIDE PRECURSORS/

We report the synthesis of acidic (Zn/Al-POM) and basic (Mg/Al-POM and Mg/Ga-POM) materials by a general route previously demonstrated only for basic LDH materials. In each case, H2W12O406- or PW11O397- pillare d materials with significant BET surface areas were obtained. Stringen t control over the M2+:M3+ ratio in the layers of the POM-pillared pro ducts was not possible, and loss of M2+ was found to be the most sever e for the Mg/Ga and Zn/Al materials. Infrared analysis indicated that complete exchange of adipate anions in the precursor material by POM a nions was achieved except for the Zn/Al analogues. Removal of the resi dual adipate anions after washing the product with a dilute base solut ion was possible, but a concomitant decrease in surface area could not be avoided.