M. Uchida et al., IMPROVED PREPARATION PROCESS OF VERY-LOW-PLATINUM-LOADING ELECTRODES FOR POLYMER ELECTROLYTE FUEL-CELLS, Journal of the Electrochemical Society, 145(11), 1998, pp. 3708-3713
Citations number
22
Categorie Soggetti
Electrochemistry,"Materials Science, Coatings & Films
We have previously reported a preparation process for the catalyst lay
er of polymer electrolyte fuel cells (PEFCs) using perfluorosulfonate
ionomer (PFSI) colloid. In this paper we report recent improvements in
this method of preparation. In the present method, a carbon-supported
platinum catalyst (Pt-C) was mixed with poor solvent for PFSI, and PF
SI solution was added to this mixture. The colloidal PFSI formed was i
mmediately adsorbed on Pt-C without coagulation. As a result, the reac
tion area was increased, the internal resistance was decreased, and th
e gaseous reactants were more readily supplied to the reaction area. W
e also studied the influence of the carbon support on the microstructu
re of the catalyst layer. We have found that the performance of a PEFC
prepared by this process with optimum carbon support and with Very lo
w platinum loading (0.1 mg/cm(2)) was superior to that prepared by our
previous process with conventional carbon support and with a 0.5 mg/c
m(2) platinum loading.