A. Scacco et al., SEGREGATION OF CE IMPURITIES IN KMGF3 SINGLE-CRYSTALS, Nuovo cimento della Societa italiana di fisica. D, Condensed matter,atomic, molecular and chemical physics, biophysics, 20(7-8), 1998, pp. 893-898
In view of the successful use of perovskite-like compounds in technolo
gical applications, a study on the segregation of the dopant in the gr
owth from the melt of single crystals of KMgF3:Ce3+ is carried out wit
h particular concern to the influence of impurity concentration and pu
lling rate. The effective segregation coefficient of Ce3+ in KMgF3 is
found to have the approximately constant value of 0.22 for solidified
fractions lower than 25% and to considerably increase in the rest of t
he growth process because of matrix evaporation.