A. Rizzi et H. Luth, ELECTRONIC GAP STATES ON GAN(0001)-(1 X-1) SURFACES STUDIED BY ELECTRON SPECTROSCOPIES, Nuovo cimento della Societa italiana di fisica. D, Condensed matter,atomic, molecular and chemical physics, biophysics, 20(7-8), 1998, pp. 1039-1045
GaN(0001)-(1 x 1) surfaces are grown by RF plasma-assisted MBE and cha
racterized in situ by electron spectroscopy. A consistent picture of t
he energy distribution of occupied and empty electronic states in the
gap of the GaN is deduced by a combined photoemission- and high-resolu
tion electron energy loss spectroscopy study. Surface electronic state
s near the valence and conduction band edges are assessed and an overa
ll picture of the wurtzite GaN surface emerges which is similar to tha
t of ZnO surfaces. Electronic states in the upper half of the forbidde
n band are assumed to be responsible for the observed upwards band ben
ding with the Fermi level pinning at E-F - E-v = (2.4 +/- 0.1) eV.