Optical emission spectroscopy with high spatial resolution was applied
for the study of plasma-material interaction in low-pressure reactive
ion etching. Atomic and molecular emission by sputtered material has
been found to be strongly localized near the surface. Excited particle
s are produced during sputtering by energetic ions, with the mechanism
s being different for atoms and molecules. In atomic secondary photon
emission, a cascade from highly excited levels is shown to be importan
t. This method can be used as a probe during plasma processing. (C) 19
97 American Institute of Physics.