SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF MIXED-LIGAND COMPOUNDS EU(S2CN(C2H5)(2))(3)(2,2'-BIPY) AND EU(S2CN(C2H5)(2))(3)(1,10-PHEN)

Citation
Vl. Varand et al., SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF MIXED-LIGAND COMPOUNDS EU(S2CN(C2H5)(2))(3)(2,2'-BIPY) AND EU(S2CN(C2H5)(2))(3)(1,10-PHEN), Journal of structural chemistry, 39(2), 1998, pp. 244-252
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224766
Volume
39
Issue
2
Year of publication
1998
Pages
244 - 252
Database
ISI
SICI code
0022-4766(1998)39:2<244:SACAMO>2.0.ZU;2-H
Abstract
Synthetic procedures were developed and X-ray diffraction analysis was performed for two mixed-ligand compounds of europium(III) with diethy ldithiocarbamate ions and 2,2'-bipyridyl (2,2'-Bipy) or 1,10-phenanthr oline (Phen): Eu(S2CN(C2H5)(2))(3)(2,2'-Bipy) (I) and Eu(S2CN(C2H5)(2) )(3)Phen (II). The structures of the complexes consist of discrete mon omer molecules; the coordination polyhedron of Eu (EuN2S6 is a node) i s a distorted dodecahedron.