EXACT CALCULATION OF THE SOLVATION ENERGY OF A PAIR OF IONS IN POLAR MEDIA WITHIN THE FRAMEWORK OF THE DIELECTRIC CONTINUUM MODEL

Authors
MIYAZAKI K TACHIYA M
Citation
K. Miyazaki et M. Tachiya, EXACT CALCULATION OF THE SOLVATION ENERGY OF A PAIR OF IONS IN POLAR MEDIA WITHIN THE FRAMEWORK OF THE DIELECTRIC CONTINUUM MODEL, The Journal of chemical physics, 109(17), 1998, pp. 7424-7430
Citations number
8
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
109
Issue
17
Year of publication
1998
Pages
7424 - 7430
Database
ISI
SICI code
0021-9606(1998)109:17<7424:ECOTSE>2.0.ZU;2-1
Abstract
The solvation energy of a pair of ions in polar media is exactly calcu lated within the framework of the dielectric continuum model. The prod uct ions are modeled as either conducting spheres with charges on thei r surfaces or spherical vacuum cavities with point charges at their ce nters. The results show that, if the two ions are close to each other, the solvation energy is different from the results known in the liter ature. (C) 1998 American Institute of Physics. [S0021-9606(98)51441-9] .