GaN films were successfully grown by the remote-plasma metalorganic ch
emical vapor deposition (RPMOCVD) system. The composition of the GaN f
ilms could be tuned from nitrogen-rich to stoichiometric growth by var
ying the mole flow rate of trimethylgallium (TMGa). A hypothesis conce
rning the collisions between excited nitrogen and TMGa was also brough
t up. The collision between excited nitrogen and TMGa influences the c
haracteristics of surface morphology, composition, growth rate, and gr
owth mechanism. The characteristics of the GaN film were optimized by
changing the growth conditions. The narrowest FWHM of the double-cryst
al X-ray rocking curve is about 0.2 degrees. Under optimized condition
s, the composition of the GaN film is almost the same as that of the r
eference GaN film grown by MOCVD.