OPTOELECTRONIC AND STRUCTURAL-PROPERTIES OF GOOD QUALITY HYDROGENATEDAMORPHOUS-SILICON CARBIDE FILMS DEPOSITED BY HOT-WIRE ASSISTED RF PLASMA DEPOSITION TECHNIQUE
S. Chattopadhyay et al., OPTOELECTRONIC AND STRUCTURAL-PROPERTIES OF GOOD QUALITY HYDROGENATEDAMORPHOUS-SILICON CARBIDE FILMS DEPOSITED BY HOT-WIRE ASSISTED RF PLASMA DEPOSITION TECHNIQUE, JPN J A P 1, 37(10), 1998, pp. 5480-5484
Hydrogenated amorphous silicon carbide (a-SiC:H) films were deposited
by using a combination of radio frequency plasma enhanced chemical vap
our deposition (RF-PECVD) and heated filament techniques with the obje
ctive of improving the quality of the films due to the possible benefi
cial effect of the latter technique. The atomic hydrogen produced via
electron (emitted from the filament) impact dissociation of the proces
s gases plays a significant role in improving the properties of the fi
lm such as the structure and bonding configuration. The electrons emit
ted from the hot filament also help in dissociation of methane molecul
es into different types of radicals. From the characterization of the
films thus produced it is seen that by the combination of the two meth
ods of deposition under optimised condition carbon is incorporated mor
e as a Si-C bond which is structurally better. These results in better
opto-electronic properties at high band gap of a-SiC:H which also sho
ws lower light induced degradation than those of the films produced by
only using the RF PECVD method.