K. Chikuma et al., WAVE-GUIDING EPITAXIAL POTASSIUM LITHIUM-NIOBATE SINGLE-CRYSTAL FILMSDEPOSITED BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION, JPN J A P 1, 37(10), 1998, pp. 5582-5587
Epitaxial potassium lithium niobate (KLN) single-crystal films were de
posited on potassium lithium tantalate (KLT) singre-crystal substrates
by low-pressure metalorganic chemical vapor deposition (MOCVD). Penta
ethoxyniobium [Nb(OC2H5)(5)] and K and Li-dipivaloylmethane [K(DPM), L
i(DPM)] were used as volatile metalorganic precursors. The crystallini
ty of the films was investigated by X-ray diffraction measurements. Re
ciprocal space mapping indicated that good epitaxial growth had been a
chieved. The film surface was smooth enough to act as a waveguide. Sev
eral guided modes were observed for both TE and TM waves by the prism
coupler method. Refractive indices of the films for various wavelength
s were determined and the phase matching property of the waveguide is
discussed. The propagation loss, estimated by the cut-back method, was
found to be 0.5 dB/cm at a wavelength of 633 nm.