Total-reflection X-ray fluorescence analysis is usually carried out us
ing a single X-ray beam to irradiate a sample surface at a glancing an
gle from one direction. We have attempted to conduct X-ray fluorescenc
e analysis using multiple glancing X-ray beams emitted from a glow dis
charge X-ray tube. Fe characteristic X-rays were used as the primary X
-rays to irradiate a thin Cr film (sample) on a flat acrylic carrier a
t multiple glancing angles. We have concluded that multiple X-ray beam
excitation is an effective method for enhancement of X-ray fluorescen
ce intensity.