Tp. Devereaux et al., ENHANCED ELECTRON-PHONON COUPLING AND ITS IRRELEVANCE TO HIGH T-C SUPERCONDUCTIVITY, Solid state communications, 108(7), 1998, pp. 407-411
It is argued that the origin of the buckling of the CuO2 planes in cer
tain cuprates as well as the strong electron-phonon coupling of the B-
1g phonon is due to the electric field across the planes induced by at
oms with different valence above and below. The magnitude of the elect
ric field is deduced from new Raman results on YBa2Cu3O6+x and Bi2Sr2(
Ca1 - xYx)Cu2O8 With different O and Y doping, respectively. In the la
tter case it is shown that the symmetry breaking by replacing Ca parti
ally by Y enhances the coupling by an order of magnitude, while the su
perconducting Te drops to about two third of its original value. (C) 1
998 Elsevier Science Ltd. All rights reserved.