SYNTHESIS AND MAGNETIC-PROPERTIES OF BINUCLEAR IRON(III) COMPLEXES CONTAINING PHOTOISOMERIZATION LIGAND

Authors
HAYAMI S INOUE K OSAKI S MAEDA Y
Citation
S. Hayami et al., SYNTHESIS AND MAGNETIC-PROPERTIES OF BINUCLEAR IRON(III) COMPLEXES CONTAINING PHOTOISOMERIZATION LIGAND, Chemistry Letters, (10), 1998, pp. 987-988
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1998
Pages
987 - 988
Database
ISI
SICI code
0366-7022(1998):10<987:SAMOBI>2.0.ZU;2-C
Abstract
Binuclear iron(III) spin-crossover complex [Fe-2(salten)(2)(az)](BPh4) (2) (az=azobis(4-pyridine)) was synthesized and characterized by X-ray single-crystal diffraction, Mossbauer spectra, magnetic susceptibilit ies and electronic spectra. This complex contains the ligand which is able to photoisomerize as a bridging ligand. The complex exhibited the spin-crossover behavior depending on temperature in solution and soli d state. Mossbauer measurements indicated that the complex exhibited r apid spin-equilibrium behavior at room temperature.