COBALT TETRAPHENYLPORPHINE ELECTROCATALYZED N2O REDUCTION IN DMF SOLUTION

Authors
TEZUKA M IWASAKI M
Citation
M. Tezuka et M. Iwasaki, COBALT TETRAPHENYLPORPHINE ELECTROCATALYZED N2O REDUCTION IN DMF SOLUTION, Chemistry Letters, (10), 1998, pp. 1017-1018
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1998
Pages
1017 - 1018
Database
ISI
SICI code
0366-7022(1998):10<1017:CTENRI>2.0.ZU;2-X
Abstract
The electrocatalytic reduction of N2O in the presence of cobalt tetrap henylporphine (CoTPP) was investigated by means of cyclic voltammetry (CV). Based on the kinetical treatment of the data, the rate constant for the electron transfer to N2O from CoTPP dianion could be determine d and the activation energy of the step was estimated as 39.5 kJ mol(- 1).