PREPARATION OF DIAZA DIOXA DITHIA CROWN P-TERT-BUTYLCALIX[4]ARENE BY S-ALKYLATION REACTIONS - USE OF METALLO-CALIX[4]ARENE COMPLEXES AS REACTION TEMPLATES

Authors
TOMAPATANAGET B PULPOKA B TUNTULANI T
Citation
B. Tomapatanaget et al., PREPARATION OF DIAZA DIOXA DITHIA CROWN P-TERT-BUTYLCALIX[4]ARENE BY S-ALKYLATION REACTIONS - USE OF METALLO-CALIX[4]ARENE COMPLEXES AS REACTION TEMPLATES, Chemistry Letters, (10), 1998, pp. 1037-1038
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1998
Pages
1037 - 1038
Database
ISI
SICI code
0366-7022(1998):10<1037:PODDDC>2.0.ZU;2-I
Abstract
New nickel-thiolato-calix[4]arene complexes were produced by mean of m etal-template synthesis employing S-alkylation of a nickel thiolato co mplex with a dichloroethyl- or a dibromoethyl-calix[4]arene derivative . Demetallation of a nickel-thiolato-calix[4]arene complex resulted in a p-tert-butylcalix[4]arene derivative containing two N-, two O- and two S-donors.