REACTIONS OF CR, MO, W, AND MN CARBONYLS WITH 3,6-DI-TERT-BUTYL-O-QUINONE UNDER THE ACTION OF ELASTIC-WAVE PULSES

Citation
Ai. Aleksandrov et al., REACTIONS OF CR, MO, W, AND MN CARBONYLS WITH 3,6-DI-TERT-BUTYL-O-QUINONE UNDER THE ACTION OF ELASTIC-WAVE PULSES, Russian chemical bulletin, 45(11), 1996, pp. 2639-2643
Citations number
6
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
11
Year of publication
1996
Pages
2639 - 2643
Database
ISI
SICI code
1066-5285(1996)45:11<2639:ROCMWA>2.0.ZU;2-H
Abstract
Solid-state reactions of Cr, Mo, W, and Mn carbonyls with 3,6-di-tert- butyl-o-benzo-quinone (Q) proceeding in molded powder-like mixtures (c arbonyl-Q) treated with purses of elastic waves were studied. The prod ucts of the reactions of Q with Cr(CO)(6), Mo(CO)(6), and W(CO)(6) are paramagnetic semiquinone complexes of Cr, Mo, and W. The formation of two semiquinone complexes with one or two manganese atoms was detecte d in the reaction of Mn-2(CO)(10) with Q.