Ai. Aleksandrov et al., REACTIONS OF CR, MO, W, AND MN CARBONYLS WITH 3,6-DI-TERT-BUTYL-O-QUINONE UNDER THE ACTION OF ELASTIC-WAVE PULSES, Russian chemical bulletin, 45(11), 1996, pp. 2639-2643
Solid-state reactions of Cr, Mo, W, and Mn carbonyls with 3,6-di-tert-
butyl-o-benzo-quinone (Q) proceeding in molded powder-like mixtures (c
arbonyl-Q) treated with purses of elastic waves were studied. The prod
ucts of the reactions of Q with Cr(CO)(6), Mo(CO)(6), and W(CO)(6) are
paramagnetic semiquinone complexes of Cr, Mo, and W. The formation of
two semiquinone complexes with one or two manganese atoms was detecte
d in the reaction of Mn-2(CO)(10) with Q.