T. Mahmood et Jh. Merkin, THE CONVECTIVE BOUNDARY-LAYER FLOW ON A REACTING SURFACE IN A POROUS-MEDIUM, Transport in porous media, 32(3), 1998, pp. 285-298
The convective boundary-layer flow on an impermeable vertical surface
in a fluid-saturated porous medium is considered where the flow result
s from the heat released by an exothermic catalytic reaction on the su
rface converting a reactive component within the convective fluid to a
n inert product. The reaction is modelled by first-order kinetics with
an Arrhenius temperature dependence. Numerical solutions of the gover
ning equations are obtained for a range of parameter values. These sho
w, for large activation energies, that localized rapid changes in wall
temperature and localized high reaction rates occur a little way from
the leading edge. Asymptotic expansions, valid at large distances fro
m the leading edge, are derived, the form that these expansions take i
s qualitatively different depending on whether or not reactant consump
tion is included in the model.