PREPARATION OF THERMOSENSITIVE MAGNETIC PARTICLES BY DISPERSION POLYMERIZATION

Citation
Xb. Ding et al., PREPARATION OF THERMOSENSITIVE MAGNETIC PARTICLES BY DISPERSION POLYMERIZATION, Reactive & functional polymers, 38(1), 1998, pp. 11-15
Citations number
5
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
ISSN journal
13815148
Volume
38
Issue
1
Year of publication
1998
Pages
11 - 15
Database
ISI
SICI code
1381-5148(1998)38:1<11:POTMPB>2.0.ZU;2-Z
Abstract
A new kind of thermosensitive magnetic particles with core/shell struc ture was prepared by copolymerization of styrene (St) and N-isopropyla crylamide (NIPAM) in the presence of Fe3O4 magnetic fluid in ethanol/w ater medium. The particles shrank above the lower critical solution te mperature (LCST) of Fe3O4/P(St-NIPAM) and swelled below the LCST in wa ter. The effect of polymerization parameters such as initiator concent ration and NIPAM/St ratio on particles was investigated. Higher initia tor concentration formed larger Fe3O4/P(St-NIPAM) particles, and the p articles size decreased as the NIPAM/St ratio increased. (C) 1998 Else vier Science B.V. All rights reserved.