Xb. Ding et al., PREPARATION OF THERMOSENSITIVE MAGNETIC PARTICLES BY DISPERSION POLYMERIZATION, Reactive & functional polymers, 38(1), 1998, pp. 11-15
A new kind of thermosensitive magnetic particles with core/shell struc
ture was prepared by copolymerization of styrene (St) and N-isopropyla
crylamide (NIPAM) in the presence of Fe3O4 magnetic fluid in ethanol/w
ater medium. The particles shrank above the lower critical solution te
mperature (LCST) of Fe3O4/P(St-NIPAM) and swelled below the LCST in wa
ter. The effect of polymerization parameters such as initiator concent
ration and NIPAM/St ratio on particles was investigated. Higher initia
tor concentration formed larger Fe3O4/P(St-NIPAM) particles, and the p
articles size decreased as the NIPAM/St ratio increased. (C) 1998 Else
vier Science B.V. All rights reserved.