(HYDROXYMETHYL)MELAMINE-OXIRANE DERIVED POLYETHEROLS - APPLICATION OFKINETIC-STUDIES TO PREDICTION OF SYNTHESIS CONDITIONS

Authors
LUBCZAK J
Citation
J. Lubczak, (HYDROXYMETHYL)MELAMINE-OXIRANE DERIVED POLYETHEROLS - APPLICATION OFKINETIC-STUDIES TO PREDICTION OF SYNTHESIS CONDITIONS, Reactive & functional polymers, 38(1), 1998, pp. 51-59
Citations number
15
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive & functional polymers → ACNP
ISSN journal
13815148
Volume
38
Issue
1
Year of publication
1998
Pages
51 - 59
Database
ISI
SICI code
1381-5148(1998)38:1<51:(DP-AO>2.0.ZU;2-K
Abstract
The study of the kinetics of addition and condensation in the (hydroxy methyl)melamine-oxirane system in DMSO solution and in the presence of triethylamine catalyst is described. The mechanisms of the reactions are presented. The kinetics parameters have been used to optimize the conditions of preparation of the s-triazine ring containing polyethero ls from pentakis(hydroxymethyl)melamine and ethylene or propylene oxid e. (C) 1998 Elsevier Science B.V. All rights reserved.