STUDY ON NEW-TYPE OF CONDUCTIVE COORDINATION COMPOUND OF C-N[M(DMIT)(2)]

A new type of conductive coordination compound of C-n[M(dmit)(2)] (M = Ni, Pd, Pt, n = 2, 1) has been obtained by introducing unsaturated he terocyclic cations (N - methylpyridine cation, N - methylquinoline cat ion and N - methylbenzothiazole cation) and trimethylphenyl ammonium i nto the system of [Ni(dmit)(2)](n-). The components and structures of these new compounds have been determined, IR spectra, ESR spectra, XPS spectra, UV spectra, magnetic susceptibilities and conductivities wer e studied. It is concluded that the charge number and distribution of the anion can be influenced by the outer cations, therefore, the elect rical property of the complexes was influenced by the cations through another way.