PALLADIUM(0) CATALYZED REARRANGEMENTS OF ALLYLIC SULFOXIMINES TO ALLYL SULFINIMIDIC ACID-ESTERS AND OPTICALLY-ACTIVE N-CBZ PROTECTED GAMMA-AMINO-ENONES

Authors
PYNE SG DAVID DM DONG ZM
Citation
Sg. Pyne et al., PALLADIUM(0) CATALYZED REARRANGEMENTS OF ALLYLIC SULFOXIMINES TO ALLYL SULFINIMIDIC ACID-ESTERS AND OPTICALLY-ACTIVE N-CBZ PROTECTED GAMMA-AMINO-ENONES, Tetrahedron letters, 39(46), 1998, pp. 8499-8502
Citations number
1
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
46
Year of publication
1998
Pages
8499 - 8502
Database
ISI
SICI code
0040-4039(1998)39:46<8499:PCROAS>2.0.ZU;2-H
Abstract
N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimid ic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected gamma-amin o-enones. (C) 1998 Elsevier Science Ltd. All rights reserved.