BIS(DI-2-PYRIDYL-N-AMINE)(PROPIONATO-O)-COPPER(II) CHLORIDE MONOHYDRATE

Authors
YOUNGME S POOPASIT K FUN HK CHINNAKALI K RAZAK IA CHANTRAPROMMA S
Citation
S. Youngme et al., BIS(DI-2-PYRIDYL-N-AMINE)(PROPIONATO-O)-COPPER(II) CHLORIDE MONOHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1221-1223
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
9
Pages
1221 - 1223
Database
ISI
SICI code
0108-2701(1998)54:<1221:BCM>2.0.ZU;2-Q
Abstract
The CuN4O2 chromophore in [CU(C10H9N3)(2)(C3H5O2)]Cl.H2O exhibits trig onal distorted square-pyramidal stereochemistry around the metal centr e, with the second O atom of the propionate group occupying a sixth co ordinating position at a longer distance of 2.640 (4) Angstrom, to giv e (4+1+1)-type coordination. The Cl- ion participates in N-H ... Cl h ydrogen bonding.