P,P']-(N,N'-DIETHYLDITHIOCARBAMATO-S,S')NICKEL(II) PERCHLORATE

Authors
RAMALINGAM K BINSHAWKATALY O FUN HK IBRAHIM AR
Citation
K. Ramalingam et al., P,P']-(N,N'-DIETHYLDITHIOCARBAMATO-S,S')NICKEL(II) PERCHLORATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1223-1225
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
9
Pages
1223 - 1225
Database
ISI
SICI code
0108-2701(1998)54:<1223:PP>2.0.ZU;2-D
Abstract
The title compound, [Ni(C5H10NS2)(C28H28P2)]ClO4, is planar. The pairs of Ni-S [2.2089 (8) and 2.2075 (8) Angstrom] and Ni-P [2.1945(7) and 2.1932(8) Angstrom] bond lengths are respectively equal, and the P-Ni- P angle [95.12(3)degrees] is large as a consequence of the flexible bu tyl chain between the two P atoms. The butyl chain lies on one side of the planar NiS2P2 chromophore and two of the phenyl rings are arrange d laterally above the plane.