DIBROMO(DIETHYL ETHER-O)(DIISOPROPYLAMINE-N)MAGNESIUM(II)

Authors
HENDERSON KW KENNEDY AR
Citation
Kw. Henderson et Ar. Kennedy, DIBROMO(DIETHYL ETHER-O)(DIISOPROPYLAMINE-N)MAGNESIUM(II), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1238-1240
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
9
Pages
1238 - 1240
Database
ISI
SICI code
0108-2701(1998)54:<1238:DE>2.0.ZU;2-D
Abstract
The coordination geometry at the Mg atom in the title complex, [MgBr2{ (C3H7)(2)NH}{(C2H5)(2)O}], is shown to be distorted tetrahedral. The p resence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [Mg1-N1 2.158(3) and Mg1-O1 2.041 (3) Angstrom].