UTYL-5-METHYL-SALICYLIDENEAMINATO)]OXOVANADIUM(IV)

Authors
HAAS G SCHIMEK GL PENNINGTON WT KOLIS JW
Citation
G. Haas et al., UTYL-5-METHYL-SALICYLIDENEAMINATO)]OXOVANADIUM(IV), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1263-1265
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
9
Pages
1263 - 1265
Database
ISI
SICI code
0108-2701(1998)54:<1263:U>2.0.ZU;2-0
Abstract
[VO(C26H34N2O2)] was synthesized in order to study its reactivity in t he oxygen-transfer catalysis of alkyl hydroperoxides to a wide array o f substituted olefins, The geometry about the V center is nearly squar e pyramidal, with an axial oxo ligand and a four-coordinate substitute d Schiff base ligand. The axial V-O bond distance of 1.592(3) Angstrom is indicative of double-bond character.