AN N-SUBSTITUTED 6,7-BENZOCOUMARIN-8,9-AZIRIDINE DERIVATIVE

Citation
K. Chinnakali et al., AN N-SUBSTITUTED 6,7-BENZOCOUMARIN-8,9-AZIRIDINE DERIVATIVE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1299-1301
Citations number
13
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
9
Pages
1299 - 1301
Database
ISI
SICI code
0108-2701(1998)54:<1299:AN6D>2.0.ZU;2-#
Abstract
In the title compound, xahydropyrano[2',3':1,2]naphth[6;7]aziridin-2-o ne, C21H18BrNO2, the tetrahydrobenzene ring adopts a flattened-boat co nformation. The aziridine plane forms dihedral angles of 80.4(1) and 5 9.1(2)degrees with the tetrahydrobenzene and N-phenyl substituent ring planes, respectively. The crystal structure is stabilized by weak C-H ... O intermolecular hydrogen bonds and pi-pi stacking interactions o f the coumarin ring.