SYNTHESES, SPECTROSCOPIC CHARACTERIZATION AND X-RAY CRYSTAL-STRUCTURES OF [HP-I-PR-3](2)[IRCL6] (1), [HP-I-PR-3](2)[IR2CL8(P-I-PR-3)] (2) AND [HP-I-PR-3][IR2CL7(P-I-PR-3)(2)] (3) - 3 POSSIBLE PRECURSORS OF THECOMPLEX IR(H)(CL)(2)(P-I-PR-3)(2) (4)

Authors
ALLEVI M CAPITANI D ETTORRE A MURA P
Citation
M. Allevi et al., SYNTHESES, SPECTROSCOPIC CHARACTERIZATION AND X-RAY CRYSTAL-STRUCTURES OF [HP-I-PR-3](2)[IRCL6] (1), [HP-I-PR-3](2)[IR2CL8(P-I-PR-3)] (2) AND [HP-I-PR-3][IR2CL7(P-I-PR-3)(2)] (3) - 3 POSSIBLE PRECURSORS OF THECOMPLEX IR(H)(CL)(2)(P-I-PR-3)(2) (4), Inorganica Chimica Acta, 282(1), 1998, pp. 17-24
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
282
Issue
1
Year of publication
1998
Pages
17 - 24
Database
ISI
SICI code
0020-1693(1998)282:1<17:SSCAXC>2.0.ZU;2-#
Abstract
A possible reaction route for Ir(H) (Cl)(2)(P-i-Pr-3)(3) (4) is propos ed. The complexes [HP-i-Pr-3](2)[IrCl6] (1), [HP-i-Pr-3](2)[Ir2Cl8(P-i -Pr-3)] (2) and [HP-i-Pr-3] [Ir2Cl7(P-i-Pr-3)(2)] (3) were investigate d. It is shown that 1, 2 and 3 are possible intermediates in the synth esis of 4. Crystallographic data are as follows: for 1 (at 298 K),a = 9.314( 1), b = 15.415(2), c= 10.073(1) Angstrom, beta=95.38(1)degrees, space group P2(1)/n; for 2 (at 298 K), a=16.382(4), b=13.968(2), c=18 .616(3) Angstrom, beta=93.62(2)degrees, space group P2(1)/c; for 3 (at 298 K), a=11.564(3), b= 12.436(3), c= 28.873(7) Angstrom, beta= 92.40 (2)degrees, space group P2(1)/c. (C) 1998 Elsevier Science S.A. All ri ghts reserved.