PHOSPHINOAMINO COMPLEXES OF COPPER(I) AND SILVER(I) - A COMBINED NMR AND IR SPECTROSCOPY, AND ELECTROSPRAY-IONIZATION AND FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY ANALYSIS

Citation
L. Crociani et al., PHOSPHINOAMINO COMPLEXES OF COPPER(I) AND SILVER(I) - A COMBINED NMR AND IR SPECTROSCOPY, AND ELECTROSPRAY-IONIZATION AND FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY ANALYSIS, Inorganica Chimica Acta, 282(1), 1998, pp. 119-122
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201693
Volume
282
Issue
1
Year of publication
1998
Pages
119 - 122
Database
ISI
SICI code
0020-1693(1998)282:1<119:PCOCAS>2.0.ZU;2-G
Abstract
Bidentate 'PN' and tetradentate 'P2N2' ligands form stable silver(I) c omplexes, which were characterized by NMR and IR spectroscopy. Conduct ivity measurements indicate an ionic nature of the compounds in soluti on. A thorough mass spectrometric study (electrospray ionization and f ast atom bombardment) of these complexes and the corresponding Cu(I) a nalogues supports the NMR and IR structural information. (C) 1998 Else vier Science S.A. All rights reserved.