THE COORDINATION ENVIRONMENT OF THE BISMUTH(III) ATOM TRIPOTASSIUM DI(NITRILOTRIACETATO)BISMUTHATE(III) DIHYDRATE

Authors
DAVIDOVICH RL TOENNESSEN LE HU SZ NG SW
Citation
Rl. Davidovich et al., THE COORDINATION ENVIRONMENT OF THE BISMUTH(III) ATOM TRIPOTASSIUM DI(NITRILOTRIACETATO)BISMUTHATE(III) DIHYDRATE, Silicon, germanium, tin and lead compounds, 21(10), 1998, pp. 601-603
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
21
Issue
10
Year of publication
1998
Pages
601 - 603
Database
ISI
SICI code
0792-1241(1998)21:10<601:TCEOTB>2.0.ZU;2-Q
Abstract
The bismuth atom in centrosymmetric tripotassium di(nitrilotriacetato) bismuthate(III) dihydrate displays cubic coordination, the atom being (N + 3O) chelated by the carboxylato group. The crystal structure cons ists of potassium cations that are linked bismuthate anions by carboxy late bridges; hydrogen bonds link the lattice water molecules with the se ions into a three-dimensional network.