ORGANOTIN PHOSPHINATES AND ARSENIATES R(2)SNA(2), R2SN(CL)A, ME3SN(O2PPH2) (R = ME, BU, A = ME2ASO2, PH2PO2) - SYNTHESIS, IR, RAMAN, MOSSBAUER AND NMR-STUDIES

Authors
SIDIBE M LAHLOU M DIOP L MAHIEU B
Citation
M. Sidibe et al., ORGANOTIN PHOSPHINATES AND ARSENIATES R(2)SNA(2), R2SN(CL)A, ME3SN(O2PPH2) (R = ME, BU, A = ME2ASO2, PH2PO2) - SYNTHESIS, IR, RAMAN, MOSSBAUER AND NMR-STUDIES, Silicon, germanium, tin and lead compounds, 21(10), 1998, pp. 605-608
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
21
Issue
10
Year of publication
1998
Pages
605 - 608
Database
ISI
SICI code
0792-1241(1998)21:10<605:OPAARR>2.0.ZU;2-P
Abstract
Derivatives of general formulae R(2)SnA(2), R2Sn(Cl)A and Me3Sn(O2PPh2 ) (R = Me, Bu; A = Me2AsO2, Ph2PO2) have been synthesized and their el emental analyses performed. From the spectroscopic data (i. r., Raman, Mossbauer and NMR) polymeric structures containing symmetrically or u nsymmetrically octahedral trans coordinated SnR2 residue and an infini te chain with a trigonal bipyramidal environment around the tin center for Me3Sn(O2PPh2) have been suggested.