Review: Teflon (PTFE) and other fluoropolymers have many properties th
at are desirable in coatings. However, due to their poor solubility it
can be very difficult to formulate coatings containing fluoropolymers
, especially if low total fluorine levels are desired. Here the author
reviews several methods to modify existing coatings by surface fluori
nation to create systems with the bulk properties of the existing coat
ing, but with a very low energy, repellant surface and low total fluor
ine levels. This is mainly achieved by designing fluorinated molecules
that stratify to the surface in the wet coating.