Communication: Soluble perfluoropolymers, readily coatable as thin fil
ms, have recently appeared on the market for premium applications such
as for pellicles and fiber optic coatings. These polymers (e.g., Tefl
on AF and Cytop) are inherently expensive because of multistep monomer
preparations, for example, of perfluorodimethyldioxole in the case of
Tenon AE Here the authors report how less expensive monomers can be u
sed to achieve similar solubility, coatability, and optical properties
. These novel polymers also have a significantly lower glass transitio
n temperature as compared to Teflon AF and Cytop.