The origins of the nonlinear indices and of the generation of the seco
nd harmonic after poling in oxide glasses containing large proportions
of TiO2 have been investigated. Within this scope, the geometry of ti
tanium oxygenated sites in glasses of TiO2-NaPO3-Na2B4O7 and TiO2-K2O-
SiO2 systems were previously determined by XAFS analysis [T. Cardinal,
E. Fargin, Y. Le Luyer, G. Le Flem, L. Canioni, P. Segonds, L. Sarger
, F. Adamietz, A. Ducasse, Nucl. Instr. and Meth. B 97 (1995) 169]. Ab
initio estimates of the first and second order microscopic polarizabi
lities for representative titanium oxygen clusters were obtained and t
hen tentatively correlated to nonlinear optical properties of the glas
ses. (C) 1998 Elsevier Science B.V. All rights reserved.