FLASH VACUUM PYROLYSIS OF STABILIZED PHOSPHORUS YLIDES - PART 13 - EXTRUSION OF PH3P FROM SULFINYL YLIDES AND REACTIVITY OF THE RESULTING SULFINYL CARBENES

Authors
AITKEN RA DRYSDALE MJ RYAN BM
Citation
Ra. Aitken et al., FLASH VACUUM PYROLYSIS OF STABILIZED PHOSPHORUS YLIDES - PART 13 - EXTRUSION OF PH3P FROM SULFINYL YLIDES AND REACTIVITY OF THE RESULTING SULFINYL CARBENES, Journal of the Chemical Society. Perkin transactions. I (Print), (20), 1998, pp. 3345-3348
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I (Print) → ACNP
ISSN journal
0300922X
Issue
20
Year of publication
1998
Pages
3345 - 3348
Database
ISI
SICI code
0300-922X(1998):20<3345:FVPOSP>2.0.ZU;2-U
Abstract
Six alpha-sulfiliyl phosphorus ylides 6 have been prepared and are fou nd upon flash vacuum pyrolysis at 500 degrees C to undergo mainly extr usion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arylsufinyl ylides loss of Ph3PO to give additional products is also observed.