COMPLEXED BRIDGING LIGAND, [M(BPCA)(2)] (M = MN(II) OR FE(II) HBPCA =BIS(2-PYRIDYLCARBONYL)AMINE), AS A BUILDING-BLOCK FOR LINEAR TRINUCLEAR COMPLEXES

Authors
KAJIWARA T ITO T
Citation
T. Kajiwara et T. Ito, COMPLEXED BRIDGING LIGAND, [M(BPCA)(2)] (M = MN(II) OR FE(II) HBPCA =BIS(2-PYRIDYLCARBONYL)AMINE), AS A BUILDING-BLOCK FOR LINEAR TRINUCLEAR COMPLEXES, Journal of the Chemical Society. Dalton transactions (Print), (20), 1998, pp. 3351-3352
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions (Print) → ACNP
ISSN journal
03009246
Issue
20
Year of publication
1998
Pages
3351 - 3352
Database
ISI
SICI code
0300-9246(1998):20<3351:CBL[(=>2.0.ZU;2-#
Abstract
The antiferromagnetically coupled trimanganese complex [Mn-II(bpca)(2) {Mn-II(hfac)(2)}(2)] (Hbpca = bis(2-pyridylcarbonyl)amine; Hhfac = hex afluoroacetylacetone) and its iron-manganese mixed metal derivative, [ Fe-II(bpca)(2){Mn-II(hfac)(2)}(2)], were synthesized by the reaction o f two equivalents of [Mn(hfac)(2)(H2O)(2)] with one equivalent of [M(b pca)(2)], the latter acting as a bridging complexed-ligand.