AN UNPRECEDENTED TRINUCLEATING BRIDGING MODE (MU(3)-ETA(1)-ETA(1)-ETA(1)) OF A TRIS(PYRAZOLYL)BORATE LIGAND IN A TRINUCLEAR SILVER(I) COMPLEX

Authors
HUMPHREY ER HARDEN NC REES LW JEFFERY JC MCCLEVERTY JA WARD MD
Citation
Er. Humphrey et al., AN UNPRECEDENTED TRINUCLEATING BRIDGING MODE (MU(3)-ETA(1)-ETA(1)-ETA(1)) OF A TRIS(PYRAZOLYL)BORATE LIGAND IN A TRINUCLEAR SILVER(I) COMPLEX, Journal of the Chemical Society. Dalton transactions (Print), (20), 1998, pp. 3353-3354
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions (Print) → ACNP
ISSN journal
03009246
Issue
20
Year of publication
1998
Pages
3353 - 3354
Database
ISI
SICI code
0300-9246(1998):20<3353:AUTBM(>2.0.ZU;2-T
Abstract
The crystal structure of [Ag-3(Tp(An))(2)][ClO4], where Tp(An) is tris [3-(2-methoxyphenyl)pyrazol-1-yl]hydroborate, shows a unique trinuclea ting bridging coordination mode for the tris(pyrazolyl)borate: each of the two ligands coordinates one pyrazolyl donor to each of the three two-coordinate Ag(I) ions, affording a triangular complex in which eac h face is capped by a mu(3)-eta(1):eta(1):eta(1)-tris(pyrazolyl)borate .