FREE-RADICAL REACTIONS OF METHYL TRIFLUOROPYRUVATE WITH ALDEHYDES

Authors
MARKOVA EA KOLOMIETS AF FOKIN AV
Citation
Ea. Markova et al., FREE-RADICAL REACTIONS OF METHYL TRIFLUOROPYRUVATE WITH ALDEHYDES, Russian chemical bulletin, 47(9), 1998, pp. 1714-1717
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
9
Year of publication
1998
Pages
1714 - 1717
Database
ISI
SICI code
1066-5285(1998)47:9<1714:FROMTW>2.0.ZU;2-J
Abstract
Methyl trifluoropyruvate reacts with aldehydes in the presence of cata lytic amounts of benzoyl peroxide at 130-140 degrees C to give ta,beta ,beta-trifluoro-alpha-(methxycarbonyl)ethyl carboxylates. UV irradiati on makes oligomerization of the initial ketoester predominant.