EXCHANGE-REACTIONS OF TETRATHIOPHOSPHATES WITH THIOPHOSPHORYL CHLORIDE

Authors
KHOKHLOV PS SOKOLOVA GD OSIPOV VN SAVENKOV NF
Citation
Ps. Khokhlov et al., EXCHANGE-REACTIONS OF TETRATHIOPHOSPHATES WITH THIOPHOSPHORYL CHLORIDE, Russian chemical bulletin, 47(9), 1998, pp. 1768-1770
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
9
Year of publication
1998
Pages
1768 - 1770
Database
ISI
SICI code
1066-5285(1998)47:9<1768:EOTWTC>2.0.ZU;2-Z
Abstract
Exchange reactions of tetrathiophosphates with thiophosphoryl chloride were studied. The exchange of thiol groups between compounds with tet racoordinated phosphorus centers proceeds at 150-220 degrees C and res ults in the formation of dialkyl trithiochlorophosphates and alkyl(ary l) dithiodichlorophosphates or their mixtures depending on the ratio o f the reagents.